Argentometric titration. Definition: The process of determining the quantity of a sample by adding measured increments of a titrant until the end-point, at which. automatic titrator will be used to perform the titration, and to obtain the titration curve. Background. Argentometric Titrations. In order for a titrimetric method to be . A titration in which Ag+ is the titrant is called an argentometric titration. Table provides a list of several typical precipitation titrations.

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A typical calculation is shown in the following example.

Email Required, but never shown. The end point is found by visually examining the titration curve. To find the moles of titrant reacting with the sample, we first need to correct for the reagent blank; thus. Calculate the titration curve for the titration of From Wikipedia, the free encyclopedia. Sign up using Facebook. The reaction in this case is. Because dichlorofluoroscein also carries a negative charge, it is repelled by the precipitate and remains in solution where it has a greenish-yellow color.

Argentometry – Wikipedia

The pH also must be less than 10 to avoid the precipitation of silver hydroxide. Chloride ions react with tjtrations I ions to give the insoluble silver chloride:. As a result, the end point is always later than the equivalence point. Prior to the end-point of the titration, chloride ions remain in excess. David Harvey DePauw University.

Titration is in aqueous solution against a solution of silver nitrate of known concentration for silver I salts that give an insoluble precipitate. A better fit is possible if the two points before the equivalence point are further apart—for example, 0 mL and 20 mL— agentometric the two points after the equivalence point are further apart.

Quantitative chemical analysis 6th ed.

Although precipitation titrimetry is rarely listed as a standard method of analysis, it may still be useful as a secondary analytical method for verifying other analytical methods. An example of a lab procedure is here 2. In the Mohr method, named after Karl Friedrich Mohrpotassium chromate is an indicator, giving red silver chromate after all chloride ions have reacted:. It is also possible to use indirect argentometric methods for determination of anions, that create insoluble salts with silver I for example phosphate PO4, arsenate AsO4 and chromate CrO4.


Anionic dyes such as dichlorofluorescein are attracted to the particles, and undergo a colour change upon adsorption, representing the end-point. Before precipitation titrimetry became practical, better methods for identifying the end point were necessary.

A blank titration requires 0. A comparison of our sketch to the exact titration curve Figure 9. There are two precipitates in this analysis: It is not suitable for titrating against chloride anions because it binds to AgCl more strongly than chloride does. Finally, we complete our sketch by drawing a smooth curve that connects the three straight-line segments Figure 9. These methods are based on back titration of excess silver with standardized thiocyanate solution.

Typically, it is used to determine the amount of chloride present in a sample.

Calculate pCl at the equivalence point using the K sp for AgCl to calculate the concentration of Cl —. Like, we use alkalimetric titration to calculate the real concentration of table vinegar. The stoichiometry of the reaction requires that. For example, after adding Again, the calculations are straightforward.

Precipitation Titrations – Chemistry LibreTexts

See the text for additional details. The scale of operations, accuracy, precision, sensitivity, time, and cost of a precipitation titration is similar to those described elsewhere in this chapter for acid—base, complexation, and redox titrations.

Home Questions Tags Users Unanswered. Eosin tetrabromofluorescein is suitable for titrating against bromideiodideand thiocyanate anions, giving a sharper end-point than dichlorofluorescein. The quantitative relationship between the titrand and the titrant is determined by the stoichiometry of the titration reaction. By using our site, you acknowledge that you have read and understand our Cookie PolicyPrivacy Policyand our Terms of Service. Calcium acetate “fixes” free chlorine, precipitates carbonates, and neutralizes the resultant solution.


Sign up using Email and Password. Calculate the volume of AgNO 3 needed to reach the equivalence point. A reaction in which the analyte and titrant form an insoluble precipitate also can serve as the basis for a titration.

Argentometric (silver nitrate) titrations overview

The Fajans method was first published in the s by Kasimir Fajans. They are most often used for determination of chloride ions, but they can be used also for other halides bromide, iodide and some pseudohalides thiocyanate. Before the equivalence point, Cl — is present in excess and pCl is determined by the concentration of unreacted Cl —.

This page was last edited on 5 Decemberat Chemistry Stack Exchange works best with JavaScript enabled. A further discussion of potentiometry is found in Chapter In the Fajans method, named after Kazimierz Fajanstypically dichlorofluorescein is used as an indicator; the end-point is marked by the green suspension turning pink. The solution needs to be near neutral, because silver arrgentometric forms at high pH, while the chromate forms H 2 CrO 4 at low pH, reducing the argetometric of chromate ions, and delaying the formation of the precipitate.

Post Your Answer Discard By clicking “Post Your Answer”, you acknowledge that you have read our updated terms of serviceprivacy policy and cookie policyand that your continued use of the website is subject to these policies. The first type of indicator is a species that forms a precipitate with the titrant.

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